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Using MAYA2000PRO to measure alcohol and its blended aqueous solution, it was found that ethanol had an absorption peak at around 217 nm in ultraviolet, which was proportional to the concentration of ethanol, while water had an absorption peak at 970 nm, which was proportional to the concentration of water.
See the report for detailed feasibility analysis, test charts and data.
Feasibility Report of Spectral Test for Ethanol Blending